Search results for "Clay nanoparticle"
showing 3 items of 3 documents
Why does vacuum drive to the loading of halloysite nanotubes? The key role of water confinement.
2019
The filling of halloysite nanotubes with active compounds solubilized in aqueous solvent was investigated theoretically and experimentally. Based on Knudsen thermogravimetric data, we demonstrated the water confinement within the cavity of halloysite. This process is crucial to properly describe the driving mechanism of halloysite loading. In addition, Knudsen thermogravimetric experiments were conducted on kaolinite nanoplates as well as on halloysite nanotubes modified with an anionic surfactant (sodium dodecanoate) in order to explore the influence of both the nanoparticle morphology and the hydrophobic/hydrophilic character of the lumen on the confinement phenomenon. The analysis of the…
Organic-nanoclay composite materials as removal agents for environmental decontamination
2019
Here we overview the recent advances in the fabrication of sustainable composite nanomaterials with decontamination capacity towards inorganic and organic pollutants. In this regards, we present the development of hybrid systems based on clay nanoparticles with different shapes (such as kaolinite nanosheets and halloysite nanotubes) and organic molecules (biopolymers, surfactants, cucurbituril) as efficient removal agents for both aliphatic and aromatic hydrocarbons. Due to their high specific surface area, clay nanoparticles have been successfully employed as fillers for composite membranes with excellent filtration capacity. The preparation of composite gel beads based on biopolymers (alg…
Halloysite nanotubes filled with salicylic acid and sodium diclofenac: effects of vacuum pumping on loading and release properties
2021
AbstractIn this work, we investigated the effects of the vacuum pumping on both the loading efficiencies and the release kinetics of halloysite nanotubes filled with drug molecules dissolved in ethanol. As model drugs, salicylic acid and sodium diclofenac were selected. For comparison, the loading of the drug molecules was conducted on platy kaolinite to explore the key role of the hollow tubular morphology on the filling mechanism of halloysite. The effects of the pressure conditions used in the loading protocol were interpreted and discussed on the basis of the thermodynamic results provided by Knudsen thermogravimetry, which demonstrated the ethanol confinement inside the halloysite cavi…